Tuesday, November 6, 2007
224-5

A Cost Effective Method to Measure Ammonia Volatilization.

Paramasivam Sivapatham1, Leandra Jones1, Ashok Alva2, and Jayaraman Kuppuswamy3. (1) Natural Sciences and Mathematics, Savannah State University, Drew Griffith Hall, P.O. Box 20600, Savannah, GA 31404, (2) USDA-ARS, USDA-ARS Vegetable and Forage Crops Research, 24106 N. Bunn Road, Prosser, WA 99350-9687, (3) Engineering Technology, Savannah State University, Hubert D 120, Savannah, GA 31404

Estimating the magnitude of ammonia (NH3) volatilization losses under different conditions is important for best management nitrogen (N) recommendations aimed to satisfy the optimal crop N requirement while minimizing N losses. Currently used field techniques to trap volatilized NH3 from soils amended with various N sources and the techniques for quantitative determination of NH3 require substantial financial resources, therefore, cannot be widely used. Thus, there is a compelling need for alternative techniques which are cost effective and applicable under wide range of conditions. The technique described in this study is a modification of the currently used two passive flux methods. The modified technique involves the use of sponge treated with oxalic acid to trap volatilized NH3 and extract NH3 from sponge with de-ionized water and determine NH3 quantitatively by ion chromatograph (IC). This improved method has been tested against the conventional technique in multiple laboratory experiments using soils amended with various N sources. These evaluations have revealed that the NH3 volatilization estimates by the proposed new technique compared favorably with those by the conventional techniques. Therefore, this study confirmed that the proposed new technique of estimation of NH3 volatilization is cost effective, less labor intensive, and is applicable for varied conditions for accurate determination of NH3 volatilization losses.